
What
is Stainless Steel?
In metallurgy, stainless steel is defined as a steel alloy with
a minimum of 10% chromium content by mass. Stainless steel does
not stain, corrode, or rust as easily as ordinary steel (it
stains less), but it is not stain-proof. It is also called
corrosion-resistant steel or CRES when the alloy type and grade
are not detailed, particularly in the aviation industry. There
are different grades and surface finishes of stainless steel to
suit the environment to which the material will be subjected in
its lifetime. Common uses of stainless steel are cutlery and
watch straps.
Stainless steel differs from carbon steel by amount of chromium
present. Carbon steel rusts when exposed to air and moisture.
This iron oxide film is active and accelerates corrosion by
forming more iron oxide. Stainless steels have sufficient amount
of chromium present so that a passive film of chromium oxide
forms which prevents further surface corrosion and blocks
corrosion spreading in the metal's internal structure.
History
The corrosion resistance of iron-chromium alloys was first
recognized in 1821 by the French metallurgist Pierre Berthier,
who noted their resistance against attack by some acids and
suggested their use in cutlery. Metallurgists of the 19th
century, however, were unable to produce the combination of low
carbon and high chromium found in most modern stainless steels,
and the high-chromium alloys they could produce were too brittle
to be practical.
In the late 1890s, Hans Goldschmidt of Germany developed an
aluminothermic (thermite) process for producing carbon-free
chromium. In the years 1904–1911 several researchers,
particularly Leon Guillet of France, prepared alloys that would
today be considered stainless steel.
Friedrich Krupp Germaniawerft built the 366-ton sailing yacht
Germania featuring a chrome-nickel steel hull in Germany in
1908. In 1911, Philip Monnartz reported on the relationship
between the chromium content and corrosion resistance. On
October 17, 1912, Krupp engineers Benno Strauss and Eduard
Maurer patented austenitic stainless steel.
Similar developments were taking place contemporaneously in the
United States, where Christian Dantsizen and Frederick Becket
were industrializing ferritic stainless.
In 1913, Harry Brearley of the Brown-Firth research laboratory
in Sheffield, England, while seeking an erosion-resistant alloy
for gun barrels, discovered and subsequently industrialized a
martensitic stainless steel alloy. The discovery was announced
two years later in a January 1915 newspaper article in The New
York Times.[3] This was later marketed under the "Staybrite"
brand by Firth Vickers in England and was used for the new
entrance canopy for the Savoy Hotel in 1929 in London.
Properties
High oxidation-resistance in ir at ambient temperature are
normally achieved with additions of a minimum of 13% (by weight)
chromium, and up to 26% is used for harsh environments. The
chromium forms a passivation layer of chromium(III) oxide
(Cr2O3) when exposed to oxygen. The layer is too thin to be
visible, and the metal remains lustrous. It is impervious to
water and air, protecting the metal beneath. Also, this layer
quickly reforms when the surface is scratched. This phenomenon
is called passivation and is seen in other metals, such as
aluminum and titanium. Corrosion resistance can however be
adversely affected if the component is used in a non-oxygenated
environment, a typical example being underwater keel-bolts
buried in timber.
When stainless steel parts such as nuts and bolts are forced
together, the oxide layer can be scraped off causing the parts
to weld together. When disassembled, the welded material may be
torn and pitted, an effect that is known as galling. This
destructive galling can be best avoided by the use of dissimilar
materials, e.g. bronze to stainless steel, or even different
types of stainless steels (martensitic against austenitic,
etc.), when metal-to-metal wear is a concern. In addition,
Nitronic alloys (trademark of Armco, Inc.) reduce the tendency
to gall through selective alloying with manganese and nitrogen.
Nickel also contributes to passivation, as do other less
commonly used ingredients such as molybdenum and vanadium.
Applications
Stainless steel’s resistance to corrosion and staining, low
maintenance, relatively low cost, and familiar luster make it an
ideal base material for a host of commercial applications. There
are over 150 grades of stainless steel, of which fifteen are
most common. The alloy is milled into coils, sheets, plates,
bars, wire, and tubing to be used in cookware, cutlery,
hardware, surgical instruments, major appliances, industrial
equipment, and as an automotive and aerospace structural alloy
and construction material in large buildings. Storage tanks and
tankers used to transport orange juice and other food are often
made of stainless steel, due to its corrosion resistance and
antibacterial properties. This also influences its use in
commercial kitchens and food processing plants, as it can be
steam cleaned, sterilized, and does not need painting or
application of other surface finishes.
Stainless steel is also used for jewellery and watches. The most
common stainless steel alloy used for this is 316L. It can be
re-finished by any jeweller and will not oxidize or turn black.
Some firearms incorporate stainless steel components as an
alternative to blued or parkerized steel. A few more expensive
revolvers like the Smith and Wesson Model 60 are milled entirely
from stainless steel. This gives a high-luster finish similar in
appearance to nickel plating but, unlike plating, not subject to
rust when scratched.
Reprinted from Wikipedia
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